Organic Reactions in Aqueous Media with a Focus on Carbon Carbon Bond

Organic Reactions in Aqueous Media with a Focus on Carbon-Carbon Bond

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1. Introduction

2. Reaction of Alkanes

3. Reaction of Alkenes

3.1. Electrophilic Additions of Alkenes

3.2. Radical Reactions of Alkenes

3.2.1. Radical Polymerization of Alkenes

3.2.2. Radical Additions

3.2.3. Radical Cyclization

3.3. Carbene Reactions

3.3.1. The Generation of Carbenes in Aqueous Media

3.3.2. The Stability of Carbenes

3.3.3. The Reaction of Carbenes with Alkenes in Aqueous Media

3.4. Transition-Metal-Catalyzed Additions

3.4.1. Polymerizations

3.4.2. Heck Reactions and Related Vinylation/Arylation

3.4.3. Hydrovinylation

3.4.4. Reaction with Arenes

3.4.5. Hydroformylation

3.4.6. Reaction with Alkynes

3.4.7. Carbonylation

3.5. Olefin Metathesis

3.5.1. Ring-Opening Metathesis Polymerization (ROMP)

3.5.2. Ring-Closing Metathesis (RCM)

3.6. Cycloaddition Reactions of Alkenes and Conjugated Alkenes

4. Reaction of Alkynes

4.1. Reaction of Terminal Alkynes

4.1.1. Alkyne Oxidative Dimerization

4.1.2. Alkyne Dimerization

4.1.3. Reaction of Alkynes with Organic Halides

4.1.4. Reaction of Alkynes with Carbonyl Compounds

4.1.5. Reaction with Imines

4.1.6. Conjugate Addition

4.2. Reaction of CtC Bonds

4.2.1. Nucleophilic Additions

4.2.2. Electrophilic Addition

4.2.3. Hydrocarboxylation

4.2.4. Hydrophosphinylation

4.2.5. Hydrometalation/Coupling

4.2.6. Pauson-Khand-Type Reactions

4.2.7. Other Transition-Metal-Catalyzed Cyclization Reactions

4.2.8. Reductive Coupling

5. Reaction of Aromatic Compounds

5.1. Electrophilic Substitutions

5.2. Radical Substitution

5.3. Oxidative Coupling

5.4. Photochemical Reactions

6. Reaction of Carbonyl Compounds

6.1. Nucleophilic Additions

6.1.1. Allylation

6.1.2. Propargylation

6.1.3. Benzylation

6.1.4. Arylation/Vinylation

6.1.5. Alkynylation

6.1.6. Alkylation

6.1.7. Reformatsky-Type Reaction

6.1.8. Direct Aldol Reaction

6.1.9. Mukaiyama Aldol Reaction

6.1.10. Hydrogen Cyanide Addition

6.2. Pinacol Coupling

6.3. Wittig Reactions

7. Reaction of R,